MEKP-PHF-60509

 
Oeko-Tex Compliance
Use of MEKP-PHF-60509 will enable button manufacturers to PASS the requirements in the Oeko-Tex 100 Class 1 Standard.
 
Superior Engineering
Our process is built on sound principles of chemical engineering design.  To maintain premium quality our process is carried out in glass lined reactors and glass extraction units.  We use a dedicated plant and a separate building unit.
 
Safety Requirements
Please see the MSDS for health and safety requirements.
All peroxides are high energy compounds and are inherently unstable.  Care should, therefore, be taken in handling and storage of these compounds.
Kerox MEKP-PHF-60509 is flammable, although the risk of auto-ignition under normal conditions is small due to its high flash point.  Once ignited it will burn slowly at first, then vigorously, and finally explode.
Kerox MEKP-PHF-60509 may undergo slow decomposition at room temperature with evolution of gaseous products which readily support combustion if ignited.  The gassing will also lead to pressure build-up leading to a possible bursting of the container.
Kerox MEKP-PHF-60509 is also catalytically decomposed by certain metallic, organic, or acidic materials.
 
Handling Spills
Care must be exercised while mopping up spillages on the production floor.  Cotton based rags or other mopping material may, at times, be contaminated with accelerators or solvents like acetone, which are commonly used for cleaning operations.  For the same reason, rags contaminated with catalyst should not be thrown carelessly into waste bins where, even in the absence of an accelerator, it may undergo spontaneous combustion.  The best way to dispose off the contaminated rags is by burning under controlled conditions.  Each country has different regulations and we urge you to consult accordingly for disposal of such waste.
 
Handling Fire
In the event of an accidental fire immediately call your local emergency response governmental department.  As a first response in such situations please be advised that conventional carbon dioxide type extinguishers will be ineffective as the catalyst produces its own oxygen to support combustion.  In such circumstances, the burning catalyst must be cooled with water, wet-sand or earth, foam based extinguishers or, if available, dry ice. All effort must be made to put out the fire before it goes out of control. 
 
MEKP-PHF-60509
Kerox offers MEKP-PHF-6059 Phthalate Free Methyl Ehtyl Ketone Peroxide (MEKP) Catalyst, as part of the 60000 Compliance Range of Products.
 
Kerox ME-50 MEKP Catalyst Specifications
Composition : Methyl Ethyl Ketone Peroxide in Phthalate FREE plasticizer.
Appearance : Clear, colorless, slightly viscous liquid.
Odor : Sharp, pungent.
Peroxide Content (%) : 50 ± 10
Active Oxygen : 9 ± 0.5
Specific Gravity at 25o C : 0.95
Critical Temperature : 80o C
Flash Point : Above 60o C
Solubility : Slightly soluble in water; freely soluble in most organic solvents.
Shelf Life : Not less than 3 months if stored below 25o C.
Storage Conditions : Store in cool place and do not expose to direct sunlight.
Standard Packing : 1 Liter, 5 Liter, 30 Liter, 35 Liter Plastic Containers.
 
Practical Safety Guidelines
Considering the relatively high hazard of organic peroxides, the safety-in-use record of Kerox MEKP-PHF-60509 has been most satisfactory.  However, careful attention must be given to the following precautions while storing and handling of Kerox MEKP-PHF-60509.
Store in a cool, dark place.
Avoid rough handling.
Keep away from direct sunlight, steam pipes, naked flame, and other sources of heat.
Smoking should be strictly prohibited in the vicinity.
All electrical installations should be flame proof type and all wiring must be concealed.
Avoid contamination with metallic, organic, or acidic materials, and in particular metal soaps and accelerators.
Avoid contamination with solvents like acetone which may react to form explosive mixtures.
Do not store accelerators and resins along with the catalyst.
Avoid contact with flammable materials such as wood, paper, fabrics, saw dust, and other cellulosic materials.
Keep the catalyst in original containers.  Do not return unused material to the container.  Keep the container closed at all times to avoid contamination.
Vent the catalyst periodically to release any internal pressure.
Large quantities of catalyst, above 50 Kg, must be stored in an isolated building away from other combustible materials.
 
Why MEKP-PHF-60509? 
MEKP available in the Indian market has traditionally been based on plasticizers and it will contribute to about 7500 ppm of phthalates when used at 2% by weight on the weight of the unsaturated polyester resin. 
At a 7500 ppm contribution of phthalates in the finished product, it will fail the Oeko-Tex 100 Class 1 Standard and also will not comply with REACH EU Regulations.  Though Oeko-Tex and REACH have restrictions on certain phthalates, buyers and importers in the European Union have restrictions on other phthalates. 
Kerox has solved the problem by engineering a new breed of MEKP products that is free from all phthalates.
Manufacturers of products using unsaturated polyester resins will be able to exclude any contribution to phthalates originating from MEKP, by using Kerox MEKP-PHF-60509 in their process.
 
Certified Quality
Kerox has been awarded the ISO 9001:2000 certification by UKAS (UK) and ANSI-RAB (USA) for the manufacture of MEKP-PHF-60509 Methyl Ethyl Ketone Peroxide Catalyst.
 
Recommendations
Gel time is a function of the type and quantity of MEKP catalyst used, Accelerator used, resin system, and the ambient temperature.  You can adjust these variable to alter the gel time.  Please see literature for further insights.
 
Storage and Handling
Kerox MEKP-PHF-60509 shows no loss of activity after 3 months if kept at 25o C.  When stored above this temperature it may suffer a slight loss of activity.  Storage stability can be considerably improved by storing at lower temperatures.  The optimum storage temperature is considered to be 10o C.  The peroxide may crystallize below 10o C forming shock-sensitive crystals.
 
First Aid Measures
Kerox ME-50 is a powerful oxidizing agent and care must be taken to avoid contact with skin, eyes, and clothing.  Protective gloves must be worn when handling the catalyst.
Skin - Immediately remove any contaminated clothing.  Wash contaminated area with soap and a running stream of water for a minimum of 15 minutes.  If irritation, or burns, or adverse symptoms develop seek medical attention.
Eyes - Serious damage can occur if the catalyst enters the eye.  As a first aid measure, if wearing contact lenses, remove them immediately.  Flush eyes with water for at least 15 minutes.  Separate the eye lids with your finger and continue thorough flushing.  If irritation, or burns, or adverse symptoms develop seek medical attention.
Ingestion - Do not induce vomiting.  Immediately seek medical attention and consult a physician and a poison control specialist.
Inhalation - Remove affected individual to fresh air.  If coughing, breathing becomes labored, irritation develops, or other symptoms develop, seek medical attention at once.  Even if symptoms develop several hours after exposure consult a physician. 

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